O2n

Reaction

Reaction

Figure 5 Decarboxylation. (Reproduced with permission from Benkovic SJ. Catalytic antibodies. Annual Review of Biochemistry 61: 29-54, © 1992, by Annual Reviews Inc.)

Reaction

Reaction

Figure 3 E2 Elimination. (Modified from Benkovic SJ. Catalytic antibodies. Annual Review of Biochemistry 61: 29-54, © 1992, by Annual Reviews Inc.)

11. The chosen reactions illustrate the more significant features of antibody catalysis. The majority of antibody-catalyzed reactions are highly stereospec-ific; the Diels-Alder condensation (Figure 2) is an example of enantioselectivity in which the normally disfavored exo product is generated over the inherent o2n-

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