ch2 ch—ch2-ch2-ch2-ch2-coo- —-v ch2 ch—ch2-ch2-ch2-ch2-coo-
Figure 10 Lipoic acid in its reduced (sulfhydryl) and oxidized (disulfide) forms. The carboxyl group on the end is attached to a lysine group on the enzyme thus forming a swinging arm that is designed to transverse remote donor-acceptor sites across the surface of the enzyme.
CH3 H o
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